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From the measured molar heat capacities and the equipartition theorem, for a diatomic gas molecule the number of degrees of freedom from rotational motion are


A) 3.
B) 0.
C) 5.
D) 2.
E) 6.

F) All of the above
G) C) and D)

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D

  You can vary the efficiency of a Carnot engine by varying the temperature of the cold reservoir while maintaining the hot reservoir at constant temperature. The curve that best represents the efficiency of such an engine as a function of the temperature of the cold reservoir is A)  1. B)  2. C)  3. D)  4. E)  5. You can vary the efficiency of a Carnot engine by varying the temperature of the cold reservoir while maintaining the hot reservoir at constant temperature. The curve that best represents the efficiency of such an engine as a function of the temperature of the cold reservoir is


A) 1.
B) 2.
C) 3.
D) 4.
E) 5.

F) All of the above
G) A) and B)

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D

  The curve on the graph of pressure versus density that best represents an isothermal process is A)  1. B)  2. C)  3. D)  4. E)  5. The curve on the graph of pressure versus density that best represents an isothermal process is


A) 1.
B) 2.
C) 3.
D) 4.
E) 5.

F) A) and E)
G) D) and E)

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A steam power plant with an efficiency of 65% of the maximum thermodynamic efficiency operates between 250oC and 40oC. What is the change in the entropy of the universe when this plant does 1.0 kJ of work?


A) 16 J/K
B) 1.7 J/K
C) 55 J/K
D) 1.7 mJ/K
E) 0.85 J/K

F) A) and C)
G) A) and B)

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A container has 0.2 mole of O2 gas and the gas is heated from 0°C to 100°C. What is the change in entropy of the gas? R = 8.314 J/mol · K.)


A) 1.82 J/K
B) 1.30 J/K
C) 0.78 J/K
D) 26.8 J/K
E) zero

F) A) and B)
G) A) and E)

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An electric power plant generates 100 MW of power at an efficiency of 35%. At what rate must water be circulated pass the condenser if the change in water temperature is not to exceed 10oC?


A) 2400 kg/s
B) 6800 kg/s
C) 3400 kg/s
D) 11300 kg/s
E) 4400 kg/s

F) B) and E)
G) C) and E)

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E

In an adiabatic reversible compression of an ideal gas, there is a decrease in


A) pressure.
B) temperature.
C) internal energy.
D) volume.
E) rms molecular velocity.

F) A) and D)
G) A) and C)

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An ideal monatomic gas has a molar heat capacity Cmp at constant pressure. What is the molar heat capacity at constant volume of an ideal diatomic gas?


A) Cmp
B) Cmp + R
C) Cmp - R
D) Cmp + 3R/2
E) Cmp - 3R/2

F) All of the above
G) B) and D)

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An ideal gas with an initial volume of 3 L at a pressure of 2 atm is compressed adiabatically until it has a volume of 2 L; then it is cooled at constant volume until its temperature drops to its initial value. The final pressure is


A) An ideal gas with an initial volume of 3 L at a pressure of 2 atm is compressed adiabatically until it has a volume of 2 L; then it is cooled at constant volume until its temperature drops to its initial value. The final pressure is A)    atm. B)  2 atm. C)  3 atm. D)  4/3 atm. E)  6 atm. atm.
B) 2 atm.
C) 3 atm.
D) 4/3 atm.
E) 6 atm.

F) A) and D)
G) D) and E)

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  An ideal gas system changes from state i to state f by paths iaf and ibf. If the heat added along iaf is Q<sub>iaf</sub> = 50 cal, the work along iaf is W<sub>iaf</sub> = 20 cal. Along ibf, if Q<sub>ibf</sub> = 40 cal, the work done, W<sub>ibf</sub>, is A)  10 cal. B)  20 cal. C)  30 cal. D)  40 cal. E)  50 cal. An ideal gas system changes from state i to state f by paths iaf and ibf. If the heat added along iaf is Qiaf = 50 cal, the work along iaf is Wiaf = 20 cal. Along ibf, if Qibf = 40 cal, the work done, Wibf, is


A) 10 cal.
B) 20 cal.
C) 30 cal.
D) 40 cal.
E) 50 cal.

F) B) and C)
G) A) and E)

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In a certain thermodynamic process, 1000 cal of heat are added to a gas confined in a cylinder. At the same time, 1000 J of work are done by the gas as it expands. The increase in internal energy of the gas is


A) zero.
B) 3186 J.
C) -239 J.
D) 5186 J.
E) 1239 J.

F) A) and C)
G) A) and B)

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An ideal gas initially at 50oC and pressure P1 = 100 kPa occupies a volume V1 = 3 L. It undergoes a quasi-static, isothermal expansion until its pressure is reduced to 50 kPa. How much heat enters the gas during this process? R = 8.314 J/mol · K = 8.206 L · atm/mol · K.


A) 116 J
B) 208 J
C) 256 J
D) 304 J
E) 416 J

F) None of the above
G) C) and E)

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A liquid is irregularly stirred in a well-insulated container and thereby undergoes a rise in temperature. Regarding the liquid as a system, you can say that


A) heat has been transferred.
B) the rise in temperature indicates work done by the system.
C) the internal energy has been unchanged.
D) the work done by the system equals the work done on the system.
E) there is a positive change in internal energy.

F) C) and E)
G) C) and D)

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One mole of an ideal gas γ = 5/3) expands adiabatically and quasi-statically from a pressure P1 = 6 atm and a temperature of 50oC to a pressure P2 = 4 atm. How much work is done by the gas during this process? R = 8.314 J/mol · K = 8.206 L · atm/mol · K.


A) 50.3 kJ
B) 56.2 kJ
C) 95.9 kJ
D) 131 kJ
E) 158 kJ

F) D) and E)
G) None of the above

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  An ideal heat engine uses 0.01 mole of gas and operates between a hot reservoir at T<sub>H</sub> = 400 K and cold reservoir at T<sub>L</sub> = 300 K, in a cycle from a→b→c→d→a. From a→b the gas undergoes an isothermal expansion, changing its volume from V<sub>a</sub> to 2.5V<sub>a</sub>. From b→c, the pressure is reduced at a constant volume. From c→d, the gas undergoes an isothermal compression, and from d→a, the pressure is increased at a constant volume until the gas is back at the original condition at a. How much heat is absorbed in going from a→b? A)  30.5 J B)  7.62 J C)  22.9 J D)  8.31 J E)  0.917 J An ideal heat engine uses 0.01 mole of gas and operates between a hot reservoir at TH = 400 K and cold reservoir at TL = 300 K, in a cycle from a→b→c→d→a. From a→b the gas undergoes an isothermal expansion, changing its volume from Va to 2.5Va. From b→c, the pressure is reduced at a constant volume. From c→d, the gas undergoes an isothermal compression, and from d→a, the pressure is increased at a constant volume until the gas is back at the original condition at a. How much heat is absorbed in going from a→b?


A) 30.5 J
B) 7.62 J
C) 22.9 J
D) 8.31 J
E) 0.917 J

F) B) and D)
G) C) and D)

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In a system composed of gas contained in a cylinder fitted with a piston, an adiabatic expansion causes the temperature of the gas to drop because


A) heat is given up by the system when the piston moves.
B) the pressure of the gas remains constant.
C) work is done on the system as the gas expands.
D) work done by the system is entirely at the expense of its internal energy.
E) heat is absorbed by the piston when it does work.

F) C) and D)
G) B) and E)

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A Carnot heat engine absorbs heat Q from a hot reservoir at 127oC and exhausts heat to a cold reservoir at 27oC. How much heat is exhausted to the cold reservoir?


A) Q
B) 27Q/127
C) 127Q/27
D) 3Q/4
E) 4Q/3

F) A) and C)
G) D) and E)

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Three moles of a gas at T = 250 K expand quasi-statically and adiabatically from an initial volume of 30 L to a final volume of 60 L. The change in entropy of the gas during this expansion is R = 8.314 J/mol·K)


A) 17.3 J/K.
B) 18.6 J/K.
C) -17.4 J/K.
D) 19.5 J/K.
E) zero.

F) A) and C)
G) A) and B)

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A system is said to go through an adiabatic process if, throughout the process,


A) it maintains a constant ratio of pressure to temperature.
B) it remains at a constant temperature.
C) it loses no heat to its surroundings and gains none from them.
D) its total energy increases.
E) it does no work on its surroundings.

F) D) and E)
G) C) and D)

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The diagram below is a schematic of a heat engine. The three quantities, QH, QL, and W are represented, respectively, by The diagram below is a schematic of a heat engine. The three quantities, Q<sub>H</sub>, Q<sub>L</sub>, and W are represented, respectively, by   A)  1, 2, 3. B)  1, 3, 2. C)  2, 3, 1. D)  3, 1, 2 E)  3, 2, 1.


A) 1, 2, 3.
B) 1, 3, 2.
C) 2, 3, 1.
D) 3, 1, 2
E) 3, 2, 1.

F) B) and E)
G) C) and E)

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